BEGIN:VCALENDAR VERSION:2.0 PRODID:-//132.216.98.100//NONSGML kigkonsult.se iCalcreator 2.20.4// BEGIN:VEVENT UID:20250928T211928EDT-04683svE1W@132.216.98.100 DTSTAMP:20250929T011928Z DESCRIPTION:Zoom link: https://mcgill.zoom.us/j/7468754607\n\nAbstract:\n\n During their lifetime\, organic aerosols will be subjected to atmospheric processing including exposure to sunlight. Photochemistry of chromophoric organic matter within aerosols can produce in-situ reactive oxygen species (ROS) capable of transforming chemical and physical properties of aerosol s\, with implications for air quality and climate. Singlet oxygen (1O2) is a well-known ROS in biology and in surface waters\, yet there is little k nowledge of its atmospheric sources and sinks\, and consequently of its ab ility to alter aerosol chemistry with implications on health and aerosol-c loud interactions.\n\n \n\nTo address this knowledge gap\, we generated se condary organic aerosols (SOA) from aromatic anthropogenic precursors in a laboratory smog chamber. We then extracted the collected SOA filters and submitted the soluble extracts to atmospherically-relevant photochemical c onditions of UVA and UVB light at room temperature. Using furfuryl alcohol as a probe for 1O2\, we determined steady-state concentrations of this ox idant using liquid chromatography and calculated 1O2 quantum yields for ea ch SOA sample. Subsequent quantification of OH radicals and peroxides allo wed for the comparison of degradation rates between ROS. We find that mole cules such as amino acids\, organo-nitrogen compounds and phenolic compoun ds have a shortened lifetime by more than half when 1O2 reactivity is take n into consideration. We further evaluated the effect of photochemical agi ng by 1O2 on the ability of SOA to act as cloud condensation nuclei\, and found that despite no 1O2 production in a-pinene SOA\, aging led to increa ses hygroscopicity. Our ongoing work is looking at the photoproduction of 1O2 in ambient PM10 filter samples in Switzerland and its potential source apportionment\, as well as sources of 1O2 production with indoor photoche mistry. The aim of this research on atmospheric 1O2 is to characterize its understudied role in aqueous aerosol chemistry.\n\nBio:\n\nNadine is an a tmospheric organic chemist interested in chemical mechanisms in the gas ph ase and in the aerosol phase. She has a BSc and MSc in organic chemistry w ith experience working in pharmaceutical industries in Canada and in Germa ny. She then obtained a PhD in atmospheric chemistry from the University o f Toronto in 2015\, working on the atmospheric fate of organo-nitrogen pol lutants. After working at an air quality consulting company in South Afric a\, she moved to Switzerland to pursue an NSERC PDF at ETH Zurich studying the role of photochemistry on aerosol-cloud interactions. In 2018\, she s tarted her independent career at ETH Zurich funded by an Ambizione grant f rom the Swiss National Science Foundation hosted in the environmental chem istry and atmospheric physics groups. In January 2021\, Nadine started as an assistant professor in Chemistry at UBC. Ongoing research interests in the NBD Group include atmospheric chemical mechanisms of pollutants and of aerosols found indoors and outdoors\, as well as cloud chemistry and the mechanism of atmospheric ice nucleation.\n DTSTART:20210202T180000Z DTEND:20210202T193000Z SUMMARY:Chemical Society Seminar: Nadine Borduas-Dedekind - Singlet oxygen in the atmosphere: Its photoproduction within aqueous organic aerosols fro m laboratory\, outdoor and indoor sources URL:/chemistry/channels/event/chemical-society-seminar -nadine-borduas-dedekind-singlet-oxygen-atmosphere-its-photoproduction-326 617 END:VEVENT END:VCALENDAR